Is there a general rule for the maximum number of Domain Name characters that search engines like to see? Are 25 characters too many? 20?
No, there's no general rule. In fact, the actual domain name plays no role in the actual search engine rankings. Each domain is given the same "chance" to rank for a particular keyword phrase.
In fact, having the keywords in the domain name have the same effect as whether the keywords are in the filename, directory name, or the subdomain: it doesn't matter where they are in the URL.
If you can get both domain names then I would buy both of them--make a decision on one to use and set up a 301 Permanent Redirect from the other(s) to the main one you're using.
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